Ozonolysis of Phenols. III. 1- and 2-Naphthol.
نویسندگان
چکیده
منابع مشابه
1-(Hydroxyiminomethyl)-2-naphthol
The title compound, C(11)H(9)NO(2), was prepared by a condens-ation reaction of 2-hydr-oxy-1-naphthaldehyde with hydroxyl-ammonium chloride in refluxing ethanol. An intra-molecular O-H⋯N hydrogen bond is observed. In the crystal structure, inter-molecular O-H⋯O and C-H⋯O hydrogen-bond inter-actions result in a two-dimensional network.
متن کامل6-Bromo-2-naphthol–piperazine (2/1)
In the title compound, 2C(10)H(7)BrO·C(4)H(10)N(2), the piperazine (pip) mol-ecule displays a chair conformation and is linked to two mol-ecules of 6-bromo-2-naphthol (bno) via O-H⋯N hydrogen bonds. Weak N-H⋯O hydrogen bonds from pip to bno mol-ecules result in chains propagating in [100]. The chains inter-act via C-H⋯π inter-actions.
متن کاملComparative detoxication. 11. Conjugations of 1-naphthol and some other phenols in houseflies and locusts.
Insects from a variety of Orders have been shown to detoxify phenols by conjugation with glucose and this mechanism has been suggested as a systematic biochemical characteristic of insects (Smith, 1955a). The phenols may be foreign compounds or may be those formed in the normal course of metabolism (Smith, 1955b, 1964; Kent & Brunet, 1959; Stay & Roth, 1962; Butenandt, Biekert, Kubler & Linzen,...
متن کاملCyclization of hydrazones of 2-acetyl-1-naphthol and 1-acetyl-2-naphthol with triphosgene. Synthesis of Spiro naphthoxazine dimers.
Cyclization of hydrazones derived from 2-acetyl-1-naphthol and 1-acetyl-2-naphthol with triphosgene gave naphtho[1,2-e]-1,3-oxazines, naphtho[2,1-e]-1,3-oxazines or their spiro dimers depending on the molar ratio of triphosgene used for the cyclization.
متن کامل1-[Morpholino(phenyl)methyl]-2-naphthol
There are two independent mol-ecules in the asymmetric unit of the title compound, C(21)H(21)NO(2), which was synthesized by the one-pot reaction of 2-naphthol, morpholine and benzaldehyde. The dihedral angles between the naphthalene ring systems and the benzene rings are 84.03 (7) and 75.76 (8)° in the two mol-ecules and an intra-molecular O-H⋯N hydrogen bond occurs in each independent mol-ecule.
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ژورنال
عنوان ژورنال: Acta Chemica Scandinavica
سال: 1962
ISSN: 0904-213X
DOI: 10.3891/acta.chem.scand.16-2421